화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Synthesis and characterization of poly (vinyl phosphonic acid-co-methacrylic acid) microbeads by suspension polymerization
초록 Poly(vinylphosphonic acid-co-methacrylic acid) microbeads were synthesized by suspension polymerization and their indium adsorption properties were investigated. The obtained microbeads were characterized by Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). The microbeads were wrinkled spheres, irrespective of the components and their sizes ranged from 100 to 200 μm. The microbeads were thermally stable up to 260°C. As the vinylphosphonic acid (VPA) content was increased, the synthetic yields and ion-exchange capacities decreased and the water uptakes increased. The optimum synthetic yield, ion-exchange capacity and water uptake were obtained at a 0.5 mole ratio of VPA. In addition, the maximum adsorption predicted by the Langmuir adsorption isotherm model was greatest at a 0.5 mole ratio of VPA.
저자 곽노석, 황택성
소속 충남대
키워드 suspension polymerization; microbead; methacrylic acid; adsorption isotherm
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