화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2951
발표분야 에너지
제목 Effect of doping materials on sinterability and electrical conductivity of LaCrO3 used as interconnector in high temperature steam electroyzer
초록 The properties of lanthanum chromites with various doping materials were investigated in terms of sintering capability and electrical conductivity. For this purpose, doped-lanthanum chromites were prepared by two types of co-preparation and Pechini methods. XRD analysis revealed that the doped-lanthanum chromites have a single phase of perovskite structure. The particle size of doped-lanthanum chromites were controlled by high energy ball milling process and were characterized by PSA. The electrical conductivity was measured by D.C. fourprobe method. From the experimental methods, we concluded that the sinterability is closely related to the second phase transformation, that is, the second phase melting above 1300 ℃ significantly promotes the sinterability. In case of electrical conductivities, Ca-doped lanthanum chromite showed better electrical conductivity than Sr-doped one.
저자 김창희, 강경수, 조원철, 박주식, 배기광
소속 한국에너지기술(연)
키워드 lanthanum chromite; ; doping material; sintering capability; electrical conductivity; high energy ball milling
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