| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
고분자합성-구조제어중합 |
| 제목 |
Synthesis and characterization of polymers having nitroanilide pendant groups |
| 초록 |
We have synthesized polymers having nitroanilide pendant groups. The polymer backbones were prepared via RAFT polymerization and nitroanilide groups were attached through post-modification. Nitroanilide group show an interesting hydrogen-bonding mode changes depending on solution environment. In polar aprotic solvents such as dimethylsulfoxide and dimethylformamide, the amide moieties of nitroanilide make intermolecular hydrogen-bond while the intramolecular hydrogen bonding is favored in less polar solvent. The nitroanilide groups incorporated in the polymers chains also showed inter- or intra-molecular interactions depending on the solvents. |
| 저자 |
박노진1, 김상율2
|
| 소속 |
1한국과학기술원(KAIST), 2KAIST |
| 키워드 |
hydrogen-bond; RAFT; nitroanilide
|
| E-Mail |
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