화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 47권 1호
발표분야 콜로이드 및 분자조립 부문위원회
제목 Biocatalytic Suprastructure for Efficient Cascade Reactions
초록 Biocatalytic cascade reactions in confined environments are known to be more efficient than open conditions. Colloidal assemblies of mesoporous suprastructure provide the catalysis with an advantageous volume-confined environment. However, the fabrication of the suprastructure assemblies under mild conditions are challenging tasks. We propose a multimodal enzyme- and photocatalysis-carrying suprastructure for efficient cascade reactions. The suprastructure of enzyme-loaded nanoparticles were prepared on polydimethylsiloxane brush-grafted surfaces through the surface-templated evaporation driven synthesis without harmful chemical reactions or solvents at ambient condition. Efficient glucose detection was achieved by biocatalyic cascade reactions in the suprastructure that provides multi-enzymes with the proximity in nano-confined channels. In conclusion, the development of our biocatalytic suprastructure can be pioneer works in modern interfacial engineering and bioreactions.
저자 이지은1, 조성민2, 김지혜1, 우상혁1, Frederik R. Wurm2, Katharina Landfester2
소속 1중앙대, 2Max Planck Institute for Polymer Research
키워드 Biocatalytic Cascade Reactions; Colloidal Suprastructures; Glucose Assay; Liquid Repellent Surfaces; Surface-templated Suprastructure
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