| 학회 | 한국공업화학회 |
| 학술대회 | 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center)) |
| 권호 | 24권 1호 |
| 발표분야 | 포스터-환경·에너지 |
| 제목 | Stable Nickel on phosphorus promoted bimodal porous alumina for enhanced coke tolerance in low-temperature steam methane reforming |
| 초록 | In this study, the Ni based hierarchical structure alumina support with low Ni content (8 wt%) and phosphorus promoter was prepared by EISA method. The phosphorus as a non-metallic element into meso-mesoporous alumina (MMA) was added to prevent its deactivation. The catalysts were prepared by increasing the P/Al molar ratios to 0, 0.02, 0.05, and 0.1, respectively. The SMR was carried out under conditions of GHSV 18,000 h-1, S/C ratio 2.5, and reaction temperature 650 °C, and the Ni/MMA-0.05P showed the highest methane conversion and hydrogen selectivity. It was confirmed that the methane conversion was higher than that of the conventional catalyst, and the activity was maintained even in the long-term durability test. Acknowledgements This study has been conducted with the support of the Korea Institute of Industrial Technology (Project no. EO200022). |
| 저자 | 최재형1, 우은석2, 제정호3, 임동하1 |
| 소속 | 1Korea Institute of Industrial Technology, 2Korea Institute of Industrial Technology / Pusan National Univ., 3Pusan National Univ. |
| 키워드 | Steam methane reforming; Hydrogen; Ni catalyst on hierarchical porous alumina; Phosphate |
