화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO))
권호 25권 1호
발표분야 포스터-무기재료
제목 Photoluminescence Enhancement of Upconversion Nanoparticle Sensitized Perovskite Quantum Dots in Metal-insulator-metal Configuration under NIR Excitation
초록 Perovskite quantum dots (PeQDs) have received much attention due to excellent properties. However, due to their low efficiency under near-infrared (NIR) light illumination, potential applications have been limited. Recently, upconversion nanoparticle (UCNP) sensitized PeQD has been reported but low quantum yield of UCNPs and photoluminescence (PL) intensity of PeQDs film have still remained as challenges. In this work, UCNP sensitized PeQDs and polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) capped gold nanorods (AuNRs) were deposited on a metallic reflector, forming AuNRs/UCNPs and PeQDs/Ag film configuration. By exploiting gap surface plasmon and localized surface plasmon effects, PL intensity of PeQDs increased under NIR excitation. Furthermore, PS-b-P2VP used as capping ligand prevented PL quenching from the direct contact of AuNRs and Ag film. This work provided a new platform to boost PL intensity of PeQD film under NIR excitation.
저자 김민주, 김영지, 현가담, 김동하
소속 이화여자대
키워드 upconversion nanoparticle; perovskite quantum dot; gap surface plasmon; upconversion enhancement
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