화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 분자전자소재 및 소자
제목 Novel melt-processible layer structured metallopolymers possessing mesophasic behavior
초록 A series of layer-structured zinc-containing metallopolymers were prepared through a solvothermal reaction of zinc acetate with 1,4-benzene dicarboxylic acid derivatives bearing various nonpolar n-alkyl groups as side chains. The resulting metallopolymers were investigated. The reaction time and the length of the alkyl substituents on the backbone have a marked effect on the mesophase structure and thermal behaviors of the metallopolymers. The metallopolymer with tetradecyloxy side chains prepared by solid-to-solid transformations within solvothermal synthesis exhibits a unique mesophasic behavior with melt tractability.
저자 최은영, 이홍준, 권오필, 이석현
소속 아주대
키워드 metallopolymer; mesophase; solvothermal synthesis; solid-to-solid transformation
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