화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-콜로이드·계면화학
제목 Structuring Bijel-templated Metal Oxide via Vaporation-induced Phase Separation (VIPS)
초록 ​Bicontinuousinterfacially jammed emulsion gels (bijels), one of the uniqueparticle-stabilized biphasic systems, have been developed to overcome thelimitation from discrete liquid droplets of typical Pickering emulsions.Herein, we introduced a bijel-templated metal-oxide structure (MO bijel) fromvaporization-induced phase separation methods. For this, the silica-dispersedternary mixture consisting of oil, water and alcohol with desired compositionwas prepared and rapid removal of alcohol triggered phase separation. Duringphase separation, in-situ surface modified silica nanoparticles trapped at theinterface and formed bijels. The bijel template of MO structure was finallyprepared with polymerization of the oil phase. We obtained MO-bijlescalcination of Sn precursor-casted bijel template to deposit SnO2 layer onbijel surface. The observation and characterization of MO bijel structuresuggested a potentialapplication including catalytic membrane, electronics, sensors.
저자 성민철1, 오민준2, Tiancheng Wang2, Kathleen Stebe2, 황길수2, 이대연2, 김진웅1
소속 1성균관대, 2Univ. of Pennsylvania
키워드 Bijels; Phase separation; Metal oxide structure
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