| 학회 | 한국공업화학회 |
| 학술대회 | 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 23권 2호 |
| 발표분야 | 포스터_에너지저장·변환 |
| 제목 | Synthesis of Multi-block copolymer based on poly(p-phenylene) for Use in Vanadium Redox Flow battery |
| 초록 | Hydrocarbon-based anion exchange membranes (AEM) have been extensively studied as alternative materials to the state-of-the-art perfluorosulfonic acid polymers such as Nafion, Aquvion. Because, the selectivity of PFSA-based membranes for balancing ions and active materials is too poor for use in VRFBs. In this study, the hydrocarbon-based multi-block copolymers for anion exchange material were synthesized by Ni(0)-catalyzed coupling polymerization, benzylic bromination and in situ quaternization, successively. In particular, the physical properties, chemical stability and VRFB performance of the synthesized membranes were investigated. |
| 저자 | 차민석1, 한승희1, 오성근2, 이장용1 |
| 소속 | 1한국화학(연), 2한양대 |
| 키워드 | vanadium redox flow battery; multiblock; poyl(p-phenylene) |
