화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 고분자구조 및 물성
제목 Silver Accordion Plasmonic Nanostructure Showing Multiple Electromagnetic Responses
초록 We realized a high-density array of accordion-shaped plasmonic silver nanorods in a large area (~ cm2) exhibiting multiple electromagnetic responses in near-infrared (NIR) and visible wavelengths. The silver accordion array was fabricated by confining lamellar-forming polystyrene-block-poly (methyl methacrylate) copolymer (PS-b-PMMA) inside cylindrical pores of aluminum oxide (AAO) template grafted by thin neutral brush layers. PS and PMMA lamellar microdomains with size of ~ 15 nm are alternatively stacked vertically along the cylindrical axis. After AAO template was removed, 5nm thick silver was thermally deposited selectively only on PS microdomains. This proposed fabrication approach demonstrated a high-density array of accordion rods with multiple resonances that could be further employed for multi-analytes detection and suggests potential employment of block copolymer self-assembly for the realization of a large-scale metamaterial with sophisticated architecture.
저자 김무성, 문정호, 노준석, 김진곤
소속 POSTECH
키워드 stacked lamellae; silver accordion nanostructures; multiple electromagnetic responses
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