학회 |
한국고분자학회 |
학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
권호 |
42권 2호 |
발표분야 |
고분자구조 및 물성 |
제목 |
Silver Accordion Plasmonic Nanostructure Showing Multiple Electromagnetic Responses |
초록 |
We realized a high-density array of accordion-shaped plasmonic silver nanorods in a large area (~ cm2) exhibiting multiple electromagnetic responses in near-infrared (NIR) and visible wavelengths. The silver accordion array was fabricated by confining lamellar-forming polystyrene-block-poly (methyl methacrylate) copolymer (PS-b-PMMA) inside cylindrical pores of aluminum oxide (AAO) template grafted by thin neutral brush layers. PS and PMMA lamellar microdomains with size of ~ 15 nm are alternatively stacked vertically along the cylindrical axis. After AAO template was removed, 5nm thick silver was thermally deposited selectively only on PS microdomains. This proposed fabrication approach demonstrated a high-density array of accordion rods with multiple resonances that could be further employed for multi-analytes detection and suggests potential employment of block copolymer self-assembly for the realization of a large-scale metamaterial with sophisticated architecture. |
저자 |
김무성, 문정호, 노준석, 김진곤
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소속 |
POSTECH |
키워드 |
stacked lamellae; silver accordion nanostructures; multiple electromagnetic responses
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E-Mail |
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