| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
분자전자 소재 및 소자(분자전자 부문위원회) |
| 제목 |
New Organic Nonlinear Optical Crystals based on N-Benzyl Pyridinium Core Structure with High Environmental Stability |
| 초록 |
We investigate new cation core structures based on N-benzyl pyridinium salt with various substituents ( X : -H ; BP1, -CH3 ; BP2, -(CH3)2 ; BP3 ) on the benzyl group for noncentrosymmetric molecular ordering in the crystalline state. In BP3 chromophore, two methyl groups on the benzyl ring can be gave more asymmetry of the chromophore shape. Among three N-benzyl pyridimium cations with p-toluenesulfonate anion, BP3 crystals exhibit acentric crystal structure (monoclinic P21 phase) with a large macroscopic optical nonlinearity. The BP3 crystals have not formed hydrated phase with water in contrast to DAST crystals. Moreover, the one-order lower solubility in water of BP3 than DAST causes good humidity resistance and can apply various crystal growth techniques. |
| 저자 |
김필주1, 정재혁1, Mojca Jazbinsek2, 권성지2, 윤호섭1, Peter Gnter2, 최수봉1, 이상민1, 권오필1
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| 소속 |
1아주대, 2ETH Zurich |
| 키워드 |
organic nonlinear optical crystal; THz application
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| E-Mail |
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