| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | 포스터-촉매 |
| 제목 | Porous organic polymer containing Phosphine rich NNN pincer motif as a catalyst support for CO2 hydrogenation |
| 초록 | CO2 is typical greenhouse gas that is often generated in daily life and is the main culprit that accelerates global warming. Research on CO2 reduction is essential to achieve one of the global goals, carbon neutral. Of the heterogenous catalysts used in hydrogenation, Porous Organic Polymer (POP)-based catalysts can be easily synthesized without complicated processes and are advantageous in industrial scale synthesis. However, the above catalyst has the disadvantage of low activity compared to the Ru catalyst supported on the Covalent Triazine Framework(CTF). To overcome these shortcomings, this study proceeded to overcome low activity by linking additional functional groups to POP-based support, leading 13 times increase in Turnover number (TON) compared with the activity of POP-based Ru catalysts without the P motif. |
| 저자 | 문석영, 윤성호 |
| 소속 | 중앙대 |
| 키워드 | Carbon Dioxide; NNN Pincer; Hydrogenation; Formic Acid; Porous Organic Polymer |
