화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 봄 (04/07 ~ 04/09, 대전컨벤션센터)
권호 46권 1호
발표분야 분자전자 부문위원회 Ⅰ
제목 Vapor-Phase Synthesis of High-k, Ultrathin Polymer Dielectrics with High Crosslinking Density for Low-Power Organic Thin-Film Transistors (OTFTs)
초록 The high dielectric constant (k) and excellent insulating performance together with the thickness down-scalability are essential requirements for polymer dielectrics to realize the stable operation of flexible, low-power electronics. In this study, we synthesized a series of copolymer dielectrics composed of two monomers of 1,4-butanediol divinyl ether (BDDVE), a cross-linker with relatively short chain length and 2-cyanoethyl acrylate (CEA) possessing a highly polar cyanide functional group. The chemical composition of the 30 nm-thick copolymer dielectrics was optimized to achieve extremely low leakage current with high dielectric constant (k ~ 7.5). High-performance, low-power organic thin-film transistors (OTFTs) with high operational stability and extreme mechanical flexibility were fabricated by exploiting the copolymer dielectric layers with optimized condition.
저자 강주연, 최준환, 임성갑
소속 한국과학기술원
키워드 polymer dielectric; high-k dielectric; polymer thin film; organic thin-film transistor (OTFT); initiated chemical vapor deposition (iCVD)
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