| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Efficient catalytic double oxidative transformation from primary amines over heterogeneous ruthenium mangania in air at room temperature |
| 초록 |
Heterogeneous catalyst (Ru(OH)x/MnO2) by simple impregnation method was carried to oxidative functional transformation of amines to nitriles at room temperature. The amine transformation in air is quite important in organic synthesis and industry because the corresponding imines or nitriles are widely used as synthetic intermediates. The supported ruthenium hydroxide (Ru(OH)x/MnO2) is easily prepared and inexpensive to use without stoichiometric amounts of harmful oxidants such as dichromate and permanganate. High selectivity and activity for the oxidation of various substrate scopes like aromatic, aliphatic, and heteroatomic amines were showed under the catalytic reaction condition. The catalysis was heterogeneous in nature and the catalyst could be easily separated from the reaction mixture. |
| 저자 |
강온유, 김정원
|
| 소속 |
강원대 |
| 키워드 |
oxdative trasformation; ruthenium mangania; room temperature; amines; nitriles
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| E-Mail |
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