화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 봄 (05/12 ~ 05/13, 전북대학교)
권호 10권 1호
발표분야 고분자
제목 Perfluorocyclobutane(PFCB) ring-containing sulfonated poly(aryl ether) membrane for fuel cell
초록 A series of sulfonated PFCB-containing biphenylene ether polymers were prepared for the fuel cell applications. Sulfonation reactions were carried out by changing the molar ratio of chlorosulfonic acid and the PFCB-containing biphenylene ether polymer under fixed time and temperature. The synthesized compounds were characterized by FT-IR, 1H-NMR, 19F-NMR, and Mass spectroscopy. A membrane with the molar ratio of PFCB-containing biphenylene ether polymer/chlorosulfonic acid(1:5.5) showed a comparable value of ion conductivity (0.102 S/cm, 80℃) with that of Nafion-115 membrane (0.1070 S/cm, 80℃).
저자 유민철1, 장봉준1, 김정훈1, 이수복1, 이용택2
소속 1한국화학(연), 2충남대
키워드 fuel cell membranes; sulfonated polymer; perfluorocyclobutane ring
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