| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis of poly(ethylene oxide) -b- poly(N-phenyl maleimide) and its application for nanopatterning |
| 초록 |
Anionic polymerization of N-phenylmaleimide (N-PMI) was carried out in the mixture of benzene/THF/DMSO at room temperature using polymeric alkoxide as an initiator. The polymeric alkoxide was obtained from n-butyllithium-initiated ring-opening polymerization of ethylene oxide (EO) in the presence of potassium tert-butoxide in the mixture of benzene/DMSO at 35℃. It was found that organolithium-initated polymerization of N-PMI in THF produced both the THF-insoluble poly(N-PMI) fraction and the THF-soluble fraction. The insoluble fraction had to arise from a different stereoregular architecture of the formed polymer. In this respect, block copolymer containing the insoluble poly(N-PMI) may be a useful material to make nanopatterned structure are polymeric template. The N-PMI fragment was deimidized in DMF or DMSO at 90℃ using hydrazine monohydrate. The results for these experiments will be presented in this study |
| 저자 |
김진흥1, 이상미1, 조영준1, 남주현1, 김훈태2, 김정안1
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| 소속 |
1경희대, 2서강대 |
| 키워드 |
Anionic; N-PMI; THF-soluble; THF-insoluble; deimidized; nanopatteren structure
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| E-Mail |
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