화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 봄 (04/05 ~ 04/07, 대전컨벤션센터)
권호 42권 1호
발표분야 분자전자 부문위원회 I
제목 Red Phosphorescent Iridium(III) Complex using Methoxynaphthalene for Solution-Processed Organic Light-Emitting Diodes
초록 We designed and synthesized a red phosphorescent iridium(III) complex, bis(2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole) Iridium(III)(acetylacetonate) [(BTMN)2Ir(acac)], for solution-processed organic light-emitting diodes (OLEDs). Photoluminescence (PL) spectra of (BTMN)2Ir(acac) showed maximum emission peak (λmax) of 599 nm in dichloromethane solution. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of (BTMN)2Ir(acac) were measured to be -5.16 and -3.08 eV, respectively. Electroluminescent (EL) spectra of (BTMN)2Ir(acac) exhibited maximum emission peak at 598 nm with a full width at half maximum (FWHM) of 76 nm and CIE coordinates of (0.59, 0.37) at 1,000 cd/m2. The device with 9% doping concentration of (BTMN)2Ir(acac) exhibited maximum luminance of 3,873 cd/m2, maximum luminous efficiency of 13.4 cd/A, power efficiency of 10.2 lm/W, and external quantum efficiency of 10.7%, respectively.
저자 장재호1, 황도훈1, 이재민2, 박정용1
소속 1부산대, 2한국화학(연)
키워드 OLEDs; Organic light-emitting diodes; Iridium complex
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