학회 | 한국화학공학회 |
학술대회 | 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
권호 | 16권 2호, p.1258 |
발표분야 | 고분자 |
제목 | Electrochromic of photo patternable conductive polythiophene having azide pendant group |
초록 | Polymerizable monomer, 2-(azidomethyl)-2,3-dihydrothieno[3,4-b][1,4]dioxine (EDOT-MZ) was synthesized based on 3,4-ethylenedioxythiophene [1,2]. The polymer from the EDOT-MZ derivatives was deposited by both electrochemical and vapor phase polymerization method to produce conductive polymer thin film [2]. FT-IR spectroscopy confirmed the photo-cross linking originated from the azide functional group. Micro scale conductive photo patterns were generated by simple UV exposure onto PEDOT-MZ film through a photomask. The electrical and optical properties of the PEDOT-MZ pattern were examined by a cyclic voltammetry and UV-vis spectroscopy. Patterned electrochromic cells were made by the direct photo-patterning method that can be easily applicable in organic electrodes, electrochromic devices, integrated circuit, electrochemical light-emitting, and solar cells. [1] A. E. Daugaard and S. Hvilsted, Macromolecules, 41, 4321 (2008). [2] J. Kim, Y. Kim, and E. Kim, Macromolecular Research, 17, 791 (2009). |
저자 | 양욱, 김유나, 김은경 |
소속 | 연세대 |
키워드 | conductive polymer; PEDOT; photo-crosslink |
원문파일 | 초록 보기 |