| 학회 |
한국공업화학회 |
| 학술대회 |
2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터) |
| 권호 |
16권 2호 |
| 발표분야 |
정보전자산업용 유기소재 |
| 제목 |
Asymmetric Polymerization and Synthesis under Chiral Nematic Liquid Crystal Reaction Field |
| 초록 |
We prepared a chemically stable chiral nematic liquid crystal (N*-LC) as an asymmetric reaction solvent for synthesis of helical polyacetylene (PA). The hierarchical helical structures of PA are precisely controlled by changing the screw degree or direction of the N*-LC reaction field. We extended the usage of N*-LC reaction filed to synthesis of helical aromatic conjugated polymers with circularly polarized fluorescence and to asymmetric synthesis such as Claisen rearrangement reaction and SN1 reaction. |
| 저자 |
고문주 |
| 소속 |
KIST 전북분원 복합소재기술(연) |
| 키워드 |
asymmetric synthesis; polyacetylene; chirality; liquid crystals
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| E-Mail |
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