| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Methodology for the Synthesis of 1,2,3-Triazole-embededCopolyether Polyol via Azide-Alkyne "Click" Functionalization |
| 초록 |
Novel synthetic methodology for the 1,2,3-triazole-embedded Copolyether polyol was provided by the wide spectrum of azide-alkyne "Click" chemistry. This click reaction has very mild reaction conditions and insensitive to water and oxygen. The triazole shave high heat of formation (△Hf°=1,2,3-triazole : 273KJ/mol) and triazole based salts are used as energetic materials. 1,2,3-Triazole-embedded polyetherdiol could be synthesized by copper-catalyzed 1,3-dipolar cycloaddition using the glycidyl azide polymer(GAP) and alkyne group containing triple bond at room temperature. The GAP or poly(GAP-co-THF) were converted easily with alkyne in high yield ＞95% in presence of TEA base to obtain the high viscous 1,2,3-triazole-embedded Copolyrther polyol without any noticed change of difunctionality. The structure and the composition of synthesized copolymers have been characterized by 1H-NMR spectroscopy. The molecular weight distribution of their Copolymer have been analyzed by GPC. |
| 저자 |
배인주, 박종혁, 지상철, 이관규, 이혜림, 이범재
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| 소속 |
충남대 |
| 키워드 |
Click chemistry; copper(I)-catalyzed 1; 3-dipolar cycloaddition; GAP; poly(GAP-THF)
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| E-Mail |
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