학회 | 한국고분자학회 |
학술대회 | 2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
권호 | 32권 1호 |
발표분야 | 고분자 합성 |
제목 | Synthesis and characterization of iron catalysts for ethylene polymerization based on 4,5-bis(imino) 2,3,7,8-tetrahydro-1H,6H-acridyl ligands. |
초록 | Here we report the synthesis and characterization of a series of iron catalysts based on 4,5-bis(imino) 2,3,7,8-tetrahydro-1H,6H-acridyl ligands. The chelating ligands were synthesized by condensation between 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione and anilines with variable 2,6 – substituents. All catalysts showed good activity towards polymerization The polymerization reactions were characterized by an induction period of few minutes depending on the structure of catalyst. |
저자 | 비누, 김일, 박대원, 하창식 |
소속 | 부산대 |
키워드 | Ethylene polymerization; late transition metal catalyst; polymer microstructure |