| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Fabrication of Polyphosphazene Containing Poly (ethylene oxide) and Polyhedral Oligomeric Silsesquioxane (POSS) Units |
| 초록 |
Polyhedral oligomeric silsesquioxane (POSS) with open-cage structure was prepared via hydrolysis and condensation reaction of trichloro(cyclopentyl)silane. And POSS with one thiol group and seven cyclopentyl groups (POSS-SH) was synthesized by the corner-capping reaction of open-cage POSS and (3-mercaptopropyl) trimethoxysilane. Polyphosphazene containing polyethylene oxide unites was fabricated by the reaction of polyphosphazene and polyethylene oxide (PEGA360) under NaH catalyst. Finally, polyphosphazene containing polyethylene oxide units was reacted with POSS-SH through UV irradiation to make polyphosphazene with polyethylene oxide and POSS units. The composition, structure, and thermal properties of the hybrid polyphosphazene were characterized by various analytical tools |
| 저자 |
박덕삼, 임정혁, 김경민
|
| 소속 |
한국교통대 |
| 키워드 |
Polyphosphazene; POSS; PEO; hybrid
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| E-Mail |
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