화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 가을 (10/23 ~ 10/25, 대구 EXCO)
권호 19권 2호, p.1874
발표분야 재료
제목 Rice husk-derived 3D-porous Si anode for high performance LIB anodes
초록 The rice husk (RH) is the outer covering of a rice kernel and protects the inner ingredients from external attack by insects and bacteria. To perform this function while ventilating air and moisture, rice plants have developed unique nanoporous silica layers in their husks through years of natural evolution. Despite the massive amount of annual production near 108 tons worldwide, so far rice husks have been recycled only for low-value agricultural items. In an effort to recycle rice husks for high-value applications, we convert the silica to silicon and use it for high performance lithium ion battery (LIB) anodes. Taking advantage of the interconnected nanoporous structure naturally existing in rice husks, the converted silicon (Si) exhibits excellent electrochemical performance as a lithium battery anode, with high reversible capacity (1615 mAh/g) and long cycle life (82% capacity retention over 500 cycles). Thus, we suggest that rice husks can be a sustainable resource for use in high-capacity lithium battery negative electrodes. This work was supported by a National Research Foundation of Korea (NRF) grants funded by the Korean Ministry of Education and Science Technology (MEST) and published in PNAS.
저자 정대수, 유명현, 박승빈, 최장욱
소속 한국과학기술원
키워드 Rice Husk; Recycling; Lithium ion battery; Anode; Silicon
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