| 학회 | 한국화학공학회 |
| 학술대회 | 2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
| 권호 | 20권 2호, p.1232 |
| 발표분야 | 고분자 |
| 제목 | Preparation of Block Copolymer of Methyl Methacrylate and Vinyl Acetate by Atom Transfer Radical Polymerization in Supercritical Carbon Dioxide |
| 초록 | Abstract: A block copolymer (PMMA-b-PVAc) of methacrylate (MMA) and vinyl acetate (VAc) was synthesized by successive atom transfer radical polymerization (ATRP) in supercritical carbon dioxide (scCO2). Vinyl acetate was polymerized in the presence of the PMMA precursor as macroinitiator, using metal halide/PMDETA complex system in supercritical carbon dioxide(scCO2). The effects of the time, pressure ratio between monomer (VAc) and macroinitiator (PMMA) were examined systematically to obtain an acceptable rate of polymerization and control over the polydispersity index (PDI) and number-average molecular weight(Mn). Acknowledgements: This research was financially supported by the Ministry of Trade, Industry & Energy (MOTIE), Korea Institute for Advancement of Technology (KIAT) and DaeGyeong Institute for Regional Program Evaluation (DGIRPE) through the Leading Industry Development for Economic Region. |
| 저자 | Kaikai Chen, Muhammad Naoshad Islam, Van Chinh Tran, 심재진 |
| 소속 | Yeungnam Univ. |
| 키워드 | Supercritical Carbon Dioxide; Block copolymer; Atom transfer radical polymerization(ATRP); Metal complex catalyst |
| 원문파일 | 초록 보기 |
