화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 고분자_포스터
제목 Galvanostatic co-electrodeposition of Cu and Pd as Catalyst for Reduction of Nitrates in Water
초록 The galvanostatic co-electrodeposition of copper and palladium from 8mM CuCl2 and 5mM PdCl2 in 0.5M HNO3 is studied using cyclic voltammetry and linear sweep voltammetry. The optimized current density for co-electrodeposition is found to beat 7mA/cm2 for 7200 seconds. The prepared electro catalyst showed promising efficiency of reducing nitrates in water at an average of 95-98% reduction from an original 100ppm concentration. This was after applying the optimized reduction current density at 12mA/cm2 for 10800seconds. SEM images reveal the surface deposits to be amorphous and with cauliflower-like structures. This indicates the catalyst as a good alternative for electrocatalys is applications. With added electrolytes, the reduction efficiency of the catalyst was enhanced by 2-3%. Soaking the prepared electrodes in tap water for 14 weeks caused possible detrimental effects on its nitrate reduction efficiency.
저자 고장면, LATIFATU MOHAMMED, 이해수, Bren Mark Felisilda, Alfred Madzamuse
소속 Hanbat National Univ.
키워드 electrodeposition; reduction of nitrate; nitrate
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