화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2005년 가을 (10/21 ~ 10/22, 인하대학교)
권호 11권 2호, p.1774
발표분야 공정시스템
제목 수정진동자를 이용한 광중합의 측정
초록 A monitoring technique of UV polymerization using a quartz crystal oscillator was explained and applied to the polymerization of 2-hydroxyethyl methacrylate with a photoinitiator of 1-chloroanthraquinone. The resonant frequency of the oscillator indicates the polymerization degree. With the different initiator concentrations and UV irradiations, the resistance increase was measured and compared with the measured outcome from FT-IR and GPC.
The experimental results indicate that higher concentration of the initiator gives larger increase of the resistance and longer irradiation leaves higher ultimate resistance. The higher resistance means higher degree of polymerization as observed with FT-IR and GPC. This demonstrates the effectiveness of the quartz crystal oscillator for the in-line measurement of polymerization degree.
저자 최희석, 김영한
소속 동아대
키워드 process sensor; UV polymerization; resonant resistance
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