| 학회 |
한국공업화학회 |
| 학술대회 |
2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터) |
| 권호 |
16권 2호 |
| 발표분야 |
포스터-촉매 |
| 제목 |
Novel titanium complexes chelated by tetradentate diamine–diethanolate ligand as catalysts for ring opening polymerization of L-lactide |
| 초록 |
Group IV metal complexes with [ONNO]-type tetradentate ligands include salan, salen, salalen, and salophan have been extensively studied. However, examples of aliphatic analogues for the salan ligand remain undeveloped in the literature. Here we report the synthesis and X-ray structure of LTi(O-i-Pr)2 and LTiCl2 complexes containing aliphatic salan ligand (HOCMe2CH2NMeCH2CH2NMeCH2CMe2OH) (LH2). Also, we will demonstrate that they could be effective catalysts for the controlled ring opening polymerization of L-lactide, as shown by the linearity of Mn of PLAs versus conversion, as well as narrow PDI values. |
| 저자 |
김소한1, 고민정2, 고영수3, 이준승2, 김영조1
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| 소속 |
1충북대, 2전남대, 3공주대 |
| 키워드 |
[ONNO]-type tetradentate; salan; titanium complex; ring opening polymerization
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| E-Mail |
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