화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 봄 (04/05 ~ 04/07, 대전컨벤션센터)
권호 42권 1호
발표분야 기능성 고분자
제목 Sharp and Bright Photoluminescence Emission of Single-Crystalline Diacetylene Nanoparticles
초록 Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through a solvent-vapor annealing process, the highly crystalline DA NPs show different structural and optical characteristics compared with the amorphous DA NPs. The single crystal structure of DA NPs was confirmed by using high-resolution transmission electron microscopy (HR-TEM) and wide angle X-ray scattering (WAXS). The luminescence color and the photoluminescence (PL) characteristics of the DA NPs were measured using color charge-coupled device (CCD) images and high-resolution laser confocal microscope (LCM). The crystalline DA NPs, emit bright green light compared with amorphous DA NPs and the main PL peak of the crystalline DA NPs exhibits relatively narrow, blue-shift phenomena due to enhanced interactions between the DA molecules in the nano-size crystal structure.
저자 이호진1, 최진호1, 김형태1, 김도형1, 김석호1, 이선종2
소속 1인하대, 2한국생산기술(연)
키워드 PCDA; Solvent-vapor annealing; Crystallinity; Photoluminescence
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