| 초록 |
Considering the many potential applications of organic electronics in portable electronic devices, it is of great importance to develop an electro-active material that possesses mechanical stability and high electronic performance. Herein, we utilize P3HT with two different regioregularities: high RR (98%) P3HT has high electronic properties but poor mechanical resilience, and low RR P3HT (68%) exhibits high elasticity and ductility but poor electronic performance. Selective crystallization of high RR P3HT induced by solution assembly allows construction of percolated networks of high RR P3HT nanowires (NWs) embedded in low RR P3HT matrix. Only 5 wt% high RR P3HT is required to reach a hole mobility comparable to that of high RR P3HT, and high RR NWs embedded in film exhibits 20 times higher elongation at break. Selective self-assembly allows us to overcome the fragile nature of highly crystalline conjugated polymers without lossing their electronic properties |
