| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | 포스터-콜로이드·계면화학 |
| 제목 | Squaric acid based metal-organic frameworks as promising adsorbents for radioactive waste storage |
| 초록 | Metal-organic frameworks (MOFs) are widely used in the field of separation and storage of radioactive waste material, with the main advantages of low cost, flexibility in network topology, geometry and chemical properties. Squaric acid with aromatic four-membered ring received its interesting name because of the unusual, almost perfect square shape. Its scaffold represents a unique moiety that has recently received considerable attention. Due to the short length of the linker, MOFs’ frameworks based on squaric acid have a small pore size (~ 4 Å) in the UiO-66 isoreticular family, which allows using them for gases capture. This work describes the synthesis of Cu based MOFs with squaric acid as a linker with subsequent implementation of the ZrF62- anion into the structure. This MOF will be used for measurement the adsorption ability of volatile elements resulting from nuclear waste treatment. The composition and comparative characteristics of MOF are given using SC-XRD, PXRD and SEM. |
| 저자 | 김빅토리야1, 김종윤2, 임상호2 |
| 소속 | 1과학기술연합대, 2한국원자력(연) |
| 키워드 | squaric acid; MOF; SC-XRD |
