화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 기능성 고분자
제목 Effect of Polymerization Kinetics on the Morphology of Polyaniline Nanostructures  
초록 A variety of nanostructures including nanofibers and nanotubes have attracted much attention because of their unique physical and chemical characteristics. In particular, the properties of the nanostructures depend on their size, shape, and dimensionality, which is in contrast with their bulk counterpart. Herein, we synthesized polyaniline nanostructures with different aspect ratios in the presence of a steric stabilizer, poly(N-vinylpyrrolidone) (PVP). The obtained PANI nanostructures were characterized by scanning electron microscopy, ultraviolet-visible spectroscopy, X-ray diffraction, and so forth. Importantly, the polymerization reaction of the nanostructures was monitored by using open-circuit potential technique, which successfully provided an in-depth insight into the dependence of the PANI morphology on the reaction kinetics at the nanometer scale.
저자 박현우, 김태준, 허진영, 강민정, 이지은, 윤현석
소속 전남대
키워드 Polyaniline; conducting polymers; nanostructures; morphology control; Polymerization Kinetics
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