| 학회 | 한국화학공학회 |
| 학술대회 | 2003년 가을 (10/24 ~ 10/25, 한양대학교) |
| 권호 | 9권 2호, p.2191 |
| 발표분야 | 에너지/환경 |
| 제목 | Study on the ClO2 production from NaClO3 to remove SOx and NOx |
| 초록 | Reaction kinetics of ClO2 production from sodium chlorate was studied in a well stirred reactor at various temperatures and molar concentrations. The kinetic rate equation was established. Effect of temperature and concentration of sodium chlorate, sodium chloride and sulfuric acid on the reaction rate was investigated by analyzing the consumption of chlorate and chloride or production of ClO2 and Cl2 using iodometric or argentometric titrations. The experimental ClO2/Cl2 ratio was found to higher than the theoretical one as expected by the reaction: 2NaClO3 + 2NaCl +2H2SO4 -> 2Na2SO4 +2ClO2 + Cl2 +2H2O ClO2/Cl2 ratio is markedly affected by ratio of NaClO3/NaCl. The optimum NaClO3/NaCl ratio for maximum ClO2/Cl2 ratio was found in the range of 2.0-4.0. Reaction mechanism and possible side reaction responsible for the enhanced ratio of ClO2/Cl2 were proposed. |
| 저자 | Deshwal Bal Raj1, 진동섭2, 김학동2, 조항대2, 최원길2, 이형근2 |
| 소속 | 1인도 A. I. J. H. M. 대, 2한국에너지기술(연) |
| 키워드 | NaClO3; SOx; NOx; SO2; NO |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
