| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
COPOLYCARBONATE OF BISPHENOL A AND 4, 4’-DIHYDROXYDIPHENYL |
| 초록 |
In comparison to a bisphenol A (BPA)-based polycarbonate (PC), a co-polycarbonate (DOD-co-PC) of BPA and 4, 4’-dihydroxydiphenyl (DOD) with 30 mol% of DOD has higher glass transition and heat deflection temperatures, lower notch-radius sensitivity, higher notched-Izod impact strength at thick section and low temperatures, more resistant to embrittlement after heat aging, better hydrolysis and environmental stress-crack resistance. To shed some light on the significant differences in the aforementioned properties of the PC and DOD-co-PC at the microscopic level, average chain length of DOD-carbonate blocks, morphology, supramolecular structure and deformation mechanisms of various DOD-co-PCs. were investigated using nuclear magnetic resonance spectroscopy, X-ray diffraction, atomic force and optical microscopy. In the present paper, we review the optical, thermal, physical/mechanical properties and analytical characterization data of DOD-co-PC together with those of PC for comparison. |
| 저자 |
James Yoon-Jin Chung1, James P. Mason2, Melanie Moethrath3, Michael Erkelenz4, Alexander Karbach5, Doris Drechsler6, Claus-Ludolf Schultz1, Ute Wollborn2
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| 소속 |
1Bayer Material Science LLC, 2PCS Business Development, 3100 Bayer Road, 4Pittsburgh, 5PA 15205, 6USA |
| 키워드 |
ㅁ |
| E-Mail |
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