| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
One-Pot In-Situ Formation of Polysulfane-Bearing Block Copolymer Nanoparticles with Tunable Size and Refractive Index |
| 초록 |
Sulfur-rich polymers have recently received keen interest as high-refractive index materials for optical devices. Since the refractive index of a sulfur-containing polymer is directly related to sulfur content, methods which allow for a precise control over the composition of sulfur-rich polymers are desired. Organic polysulfanes constitute an attractive class of sulfur-rich monomers for high refractive index materials. Controlled polymerization methods for organic polysulfanes, however, have been limited due to the low S-S bond energy of polysulfanes. Herein, we report a novel sulfur-rich block copolymer (BCP) through living ring-opening metathesis polymerization of polysulfane bearing monomer. Due to low solubility intrinsic to sulfur-rich polymers, the BCPs undergo in-situ self-assembly into well-defined nanoparticles with highly uniform size. By varying the length of the sulfur-rich block, the size of nanoparticle as well as the refractive index of the BCP film could be controlled. |
| 저자 |
조윤식1, 임지우1, 강은혜1, 양상희1, Jeffrey Pyun2, 최태림1, 차국헌1
|
| 소속 |
1서울대, 2Univ. of Arizona |
| 키워드 |
ROMP; Sulfur; Refractive Index
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| E-Mail |
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