화학공학소재연구정보센터
학회 한국재료학회
학술대회 2018년 가을 (11/07 ~ 11/09, 여수 디오션리조트)
권호 24권 2호
발표분야 3. 에너지 저장재료 실시간 분석 심포지엄(In Situ/Operando Analysis of Energy Storage)-오거나이저: 이현욱 교수(UNIST)
제목 Single-level spectromicroscopy for electrochemical systems : lithium-ion batteries, fuel cells, and microbial fuel cells.
초록  Electrochemistry plays a significant role in energy storage and conversion technologies, such as lithium-ion batteries, fuel cells, and microbial fuel cells. Because of porous and heterogeneous nature of the electrodes in these applications, the conventional current-voltage measurement shows certain limit in untangling complexity of electrochemical reactions (charge transfer, mass transport, chemical reactions and so on). Here in my talk, I will introduce the in-situ electrochemical platform combined with synchrotron-based X-ray spectromicroscopy which visualizes nanoscale charge transfer and electrochemical reactions of individual battery particles.[1,2] Within individual particles, spatial variations in the electrochemical reaction rate control lithium ion insertion pathway. I will also discuss how this technique is expansively applied to other electrochemical systems in my group.  

[1] J. Lim et al “Origin and Hysteresis of Li Compositional Spatio-Dynamics within Battery Primary Particles”, Science, 2016, 353, 566-571
[2] Y. Li et al “Fluid-enhanced Surface Diffusion Controls Intraparticle Phase Transformations” Nature Materials, 2018 in press
저자 Jongwoo Lim
소속 Department of Chemistry
키워드
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