화학공학소재연구정보센터
학회 한국재료학회
학술대회 2019년 봄 (05/15 ~ 05/17, 평창 알펜시아 리조트)
권호 25권 1호
발표분야 특별심포지엄4. 페로브스카이트/실리콘 탠덤 태양전지 기술-오거나이저:김동환(고려대)/이해석(고려대)
제목 A Highly Efficient Monolithic Perovskite/Si Tandem Solar Cell with a Three-Terminal Characterization Platform
초록 Measuring perovskite/Si tandem cells’ photovoltaic properties is challenging due to intrinsic and extrinsic issues such as the monolithic series connection feature and the spectral mismatch of most commercial solar simulators. Here, we report a simple but effective strategy that involves the application of three-terminal (3-T) architecture to monolithic perovskite/Si tandem cells for comprehensive characterization while circumventing the spectral mismatch issue. We demonstrate that the current density-voltage characteristics and the external quantumefficiency (EQE) of each subcell can be measured independently using 3-T architecture without any light/potential bias. In addition, a comprehensive study of electron dynamics, such as charge recombination kinetics of subcells, has been performed. As a result of reducing optical losses and precise current matching, the monolithic perovskite/Si tandem cell exhibits a power-conversion efficiency of 23.5% (23.1% corrected by EQE) and remarkable stability by maintaining 97% of its initial value after 100 days.
저자 김진영
소속 서울대
키워드 perovskite; Si; tandem; solar cell
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