학회 |
한국공업화학회 |
학술대회 |
2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터) |
권호 |
15권 1호 |
발표분야 |
촉매 |
제목 |
Spectrofluorimetric Determination of Levodopa Through Ternary Complex Formation With Europium(III) and Ethylenediaminetetraacetic Acid |
초록 |
A sensitive spectrofluorimetric method was developed for the determination of levodopa based on the luminescence enhancement of the ternary complex of Eu3+ in the presence of ethylenediaminetetraacetic acid (EDTA). It was found that the complex exhibited intense fluorescence peak at 591 and 613 nm with excitation at 372 nm corresponding to the 5D0-7F1 and 5D0-7F2 transition of Eu3+ ion, respectively. Under optimum conditions, the enhanced fluorescence intensity was proportional to the concentration of levodopa in the range of 3×10-9 to 2.5×10-7 mol L-1 with the limit of detection 4.37×10-10 mol L-1. The proposed method offers higher sensitivity and selectivity to determine levodopa in pharmaceutical and biological analysis. |
저자 |
KAMRUZZAMAN MD1, MD R-Mahmnur Alam1, 김소연1, 조해진1, 이상학1, 김영호1, 김성홍2
|
소속 |
1경북대, 2한국기초과학지원(연) |
키워드 |
Europium; Levodopa; Ethylenediaminetetraacetic Acid; Spectrofluorimetry
|
E-Mail |
|