| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
에너지저장변환_포스터 |
| 제목 |
UV-curable gel polymer electrolytes based on PEO-PPO tetra block copolymer and ionic liquid for supercapacitor |
| 초록 |
Gel polymer electrolytes (GPE) seem to be promising in recent years by possessing the advantages of both liquid and solid electrolytes such as high ionic conductivity, good mechanical integrity, flexibility, fredom from the leakage of liquid. In this study, UV-curable precursor was synthesized by reacting terminals of PEO-PPO tetra block copolymer (Tetronic90R4) with 4-vinylbenzyl chloride. The precursor was mixed with ionic liquid and photoinitiators, and the mixtures were fabricated into GPE membranes by casting and UV-curing process. The resulting GPE showed a high ion conductivity over 2.0 × 10-3 S/cm at room temperature and good elongation property of 50%. thermal propertis were evaluated by DSC and TGA. Electrochemical properties were characterized using cyclic voltammetry (CV), charge-discharge and electrochemical impedance spectroscopy (EIS) test. |
| 저자 |
김지희1, 한재희1, 김태호1, 김형중2, 홍영택1
|
| 소속 |
1한국화학(연), 2공주대 |
| 키워드 |
supercapacitor; UV-curing; Gel Polymer Electrolyte
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| E-Mail |
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