| 초록 |
Among various coating strategies, metal phenolic networks (MPN) has gathered prominent attention owing to a wide variety of new functionalities to various substrates through its simple mixing process. However, MPN have critical drawbacks in the aspect that its MPN network is destroyed during thermal reduction process due to its own thermal decomposition property, and thus it cannot provide electrical characteristics with the surface of target substrates. Herein, to overcome these hurdles for imparting electrical properties, we have developed carbonizable MPN film through polymerization of MPN. Above all, we provide the milestone for applying MPN system to various kinds of energy-related researches via identifying its polymerization mechanism. From the point of view, we attempt MPN to apply to silicon for anode of lithium ion battery, as a result, we could successfully synthesize carbon-metal hybrid shell on silicon nanoparticles for highly capacitive/stable anode materials. |
