화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 환경·에너지_포스터
제목 Volumetric and optical studies of binary and ternary mixture of diisopropyl ether, benzene and hexane.
초록 Experimentally measured data of various thermophysical properties of possible mixtures containing oxygenates and components of gasoline such as alkanes, aromatics over a wide temperature range, is very helpful for formulation of environmental friendly fuel, petrochemical additives. In this work, Density and refractive indices of the binary and ternary liquid mixtures of diisopropyl ether, benzene and n-hexane were experimentally measured from 298.15 K to 318.15 K over the entire composition range. Excess molar volume and deviation in refractive index of binary and ternary mixtures were fitted to the Redlich-Kister equation and the Singh equation respectively. The excess volume data of binary and ternary mixtures have also been interpreted using Prigogine-Flory-Patterson theory. Various mixing rules were used for theoretical determination of refractive indices of the binary and ternary mixtures. Temperature effects were also studied in terms of molecular interactions.
저자 박소진1, Manju Rani2, Rekha Devi2, Sanjeev Markin2
소속 1충남대, 2DCR Univ. of Science and Technology
키워드 Excess molar volume; refractive index; diisopropyl ether; benzene; n-hexane.
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