화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 분자전자 부문위원회
제목 Enhancement of Photovoltaic performance in Dye-sensitized solar cells with the TiO2 passivation layer
초록 The TiO2 thin film layers were introduced with the spin-coating method between FTO electrode and TiO2 photoanode in dye sensitized solar cell (DSSC) to prevent electron back migration from the FTO electrode to electrolyte. The DSSC containg different thickness of TiO2 thin film (10~30, 40~60 and 120~150 nm) were prepared and photovoltaic performances were analysed with I-V curves and electrochemical impedance spectroscopy. The maximum cell performance was observed in DSSC with 10~30 nm of TiO2 thin film thickness (11.92 ㎃/㎠, 0.74 V, 64 %, and 5.62 %) to compare with that of pristine DSSC (11.09 ㎃/㎠, 0.65 V, 62 %, and 4.43 %). The variation of photoelectric conversion efficiency of the DSSCs with different TiO2 thin film thickness was discussed with the analysis of crystallographic and microstructural properties of TiO2 thin films.
저자 이정관, 정대영, 김영락, 김재홍
소속 영남대
키워드 DSSC; TiO2 thin film; passivation layer; sol-gel method
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