화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_환경·에너지
제목 Syntheses and Tribological Characteristics of Alkanediol Derivatives Containing Dialkyldithiophosphoric Acid
초록 Zinc dialkyldithiophosphate(ZDDP) is a lubricant additive, which is most widely used due to its economics, performance of antioxidant, prevent of abrasion, and etc. But ZDDP contains heavy metals such as zinc, manganese, increasing the emission of heavy metal contamination of soil and ocean. This study synthesised anti-wear additives without heavy metals in a simple and efficient manner by using alkanediol derivatives. A four‐ball wear test was performed to examine tribological performance in relation to the carbon chain length of the alkanediol for the synthesised additives (B8P4, B8P6, B8P9, B8P11, and B8P13), the number of carbons for principal alkyl chain was varied from 4 to 13. The wear scar diameter(WSD) was 0.459 mm for 4 carbons, 0.472 mm for 6, 0.461 mm for 9, 0.480 mm for 11 and 0.468 mm for 13. It was confirmed that there was no significant difference. Among these, a comparison test of the properties of B8P9 and ZDDP was carried out.
저자 남석현1, 고경민1, 조정은2, 김영운1, 정노희2, 강호철1
소속 1한국화학(연), 2충북대
키워드 lubricant additives; tribology; 4-ball test; alkanediol; dialkyldithiophosphoric acid (DDP)
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