화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 가을 (10/24 ~ 10/25, 한양대학교)
권호 9권 2호, p.2073
발표분야 분체공학
제목 Preparation of High brightness BaMgAl10O17:Mn Green Phosphor particles with a spherical shape using a spray pyrolysis process
초록 Mn-doped barium magnesium aluminates (BaMgAl10O17:Mn, BAM:Mn) as a green phosphor for plasma display panels (PDPs) were prepared by spray pyrolysis. The content of Mn activator was optimized in terms of the brightness and the decay time. Also, in order to improve the luminescence intensity of BAM:Mn phosphor, some portion of magnesium was substituted by strontium. So, the emission intensity of BAM:Mn phosphor under vacuum ultraviolet (VUV) excitation was monitored with changing the amount of strontium and found to be maximum when the Sr content at a fixed Mn concentration was 30 at. % with respect to Mg element. It was observed that both the decay time and the color purity of BAM:Mn green phosphor could be improved by substituting Mg with Sr. We have also tried to further improve the luminescent intensity of BAM:Mn green phosphor, which was successfully achieved by the codoping of Eu. Finally, the optimized Mn-doped BAM green phosphor had higher photoluminescence intensity than that of commercial BAM:Mn particles as well as Zn2SiO4:Mn phosphor.
저자 이현우1, 정경열2, 강윤찬2, 양영석1
소속 1우석대, 2한국화학(연)
키워드 Green Phosphor; Spray; Polycation; Luminescence
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