| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 | 12권 1호, p.785 |
| 발표분야 | 열역학 |
| 제목 | Phase Behavior of Polymethylmethacrylate in HCFC-22 and HCFC-22 + CO2 in Supercritical State |
| 초록 | We measured the cloud point using the variable volume cell apparatus for Poly(methly methacrylate)(PMMA) in dimethylether(DME) and carbondioxide at high pressure. In this work, we measured cloud points using an apparatus with variable volume cell to get data on the solubility of PMMA in various solvents such as dimethylether(DME)and CO2. PMMA was dissolved well in the two solvents below 27MPa, and the cloud points of this were measured with the concentrations in solvents. The solubility of PMMA was not concerned with concentrations of PMMA and exhibited LCST behavior in each solvent. We also investigated the effect of CO2 on the cloud point of PMMA as adding CO2 which is non-polar into each solvent. The cloud point pressure of PMMA increased proportionally to the amount of CO2 added at the same temperature. According to this result, it was known that CO2 could be used as an anti-solvent, and the cloud point of PMMA could be controlled by changing the concentration of CO2. |
| 저자 | 김제일1, 이윤우2, 유기풍1, 임종성1 |
| 소속 | 1서강대, 2서울대 |
| 키워드 | LCST; Cloud point |
| 원문파일 | 초록 보기 |
