화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 봄 (04/25 ~ 04/26, 순천대학교)
권호 9권 1호, p.934
발표분야 이동현상
제목 Relationship between Rheological Behavior and Microstructure of Cation Surfactant Solutions
초록 In this research, rheological and rheo-optical measurements were performed to examine the relationship between rheological behavior and microstructure evolution of dilute and semi-dilute equimolar cetylpyridinium chloride(CPyCl)/sodium salicylate (NaSal) and cetyltrimethylammonium bromide (CTAB)/ NaSal solutions under shear flow. In the study of zero shear viscosity with concentration of CPyCl/NaSal and CTAB/ NaSal solutions, it was observed that the zero shear viscosity shows abrupt change at C* and C**, and this is believed to be caused by the switching of relaxation mechanism with concentration of the solutions at those concentration. To understand how the shear induced structure of CPyCl/NaSal and CTAB/ NaSal wormy micellar solutions affect the shear viscosity and wall slip velocity, birefringence was measured.
Acknowledgement : This study was supported by research grants from the KOSEF through the Applied Rheology Center (ARC), an official KOSEF-created engineering research center (ERC) at Korea University, Seoul, Korea.
저자 성기범, 한민수, 김종엽
소속 고려대
키워드 Zero shear viscosity; Wall slip velocity; Rheo-optics; Shear induced structure
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