화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 고분자가공/복합재료
제목 Three-dimensional graphene/transition metal alloys from gelatin-based hydrogel for Zinc air battery
초록 A study on stable and efficient bifunctional oxygen reduction/evolution electrocatalysts is mightily important in rechargeable Zn-air battery. In this work, we develop in-situ grown few-layers graphene-decorated transition metal alloys on nitrogen-doped carbon sheets(3DGM-NC) from anionic gelatin-based hydrogels with cationic transition metal particles for high performance Zn-air battery. This bifunctional catalyst achieves a positive half-wave potential of 0.947 V (vs reversible hydrogen electrode, RHE) for oxygen reduction reaction, and a operating potentials of 1.67 V at a 10 mA/cm2 of oxygen evolution reaction with high stability for 10 hours due to stable graphene structure and synergetic effects of transition metal alloys and nitrogen-containing functional groups. This study suggests new opportunities to develop new design and synthesis for energy conversion or storage industries.
저자 황종하, 장지현
소속 울산과학기술원
키워드 graphene; transition metal alloy; gelatin; electrocatalyst; Zn-air battery
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