화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2004년 봄 (04/23 ~ 04/24, 공주대학교)
권호 10권 1호, p.8
발표분야 고분자
제목 Evolution of Stress-Driven Pattern in Thin Bilayer Films: Spinodal Wrinkling
초록 Wrinkle formation in layered bulk systems is a well known phenomenon. Up to now, however, the wrinkle formation is believed to take place spontaneously by the abrupt compressive stress and not much is known about the dynamics. Here we report full-scale evolution of the wrinkle pattern that is driven by an instability, which is initiated by thermal stress in a thin bilayer film of an elastic metal on a viscoelastic polymer. Although the origin is different, transition of an initial island-like pattern to a labyrinthine structure without any change in wavelength (q ~ t_0) and the overall evolutionary process are strikingly similar to those in the spinodal system but the process is robust and takes place on a long time scale (about 10 days). The change into mountainous topography in late stage is accompanied by an increase in length scale from an initial wavelength to another. This change due to relaxation of the confined polymer that results in a transition from elastic- to viscous-like behavior induces wave coarsening (q ~ t_-1.04 ± 0.08) and macroscopic roughening.
저자 유필진, 이홍희
소속 서울대
키워드 spinodal wrinkling; bilayer; thin film; instability; stress; buckling; viscoelastic; elastic
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