| 학회 | 한국화학공학회 |
| 학술대회 | 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터) |
| 권호 | 19권 1호, p.2 |
| 발표분야 | 고분자 |
| 제목 | Solid-State Polymerization of High Temperature Nylon |
| 초록 | Solid-state polymerization is one of promising polymerization method among other methods, since it needs no solvent, environmentally green process to high molecular weight polymer. The effect of Nylon-6,T (T from terephthalic acid/TPA) composition on copolyamide with Nylon-4,6 and Nylon-4,T was examined using solid-state polymerization with nitrogen-steam mixing sweep fluid. At each reaction temperature, polymer from higher composition of Nylon-6,T always have slower polymerization rate compare to polymer from lower composition of Nylon-6,T in same solids-state polymerization condition. 2,5-furandicarboxylic acid (FDCA) is well known as a potential replacement for terephthalic acid (TPA) compound. The effect of replacing terephthalic acid compound using 2,5-furandicarboxylic acid were examined on copolyamide of Nylon-4,F (F from FDCA) and Nylon 4,6; which previous study about copolyamide of Nylon-4,T and Nylon-4,6 was already published. Polymerization rate of polymer contains FDCA compound were lower than polymerization rate of polymer contains TPA compound. |
| 저자 | ENDAH YOHANA KURNIA1, 김영준2, 이홍식2, 김재훈2 |
| 소속 | 1Univ. of Science and Technology, 2한국과학기술(연) |
| 키워드 | solid-state polymerization; FDCA; copolyamide; terephthalic acid |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
