화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 고분자 구조 및 물성
제목 Localized Surface Plasmon Resonance Properties of Au Nanoparticles/Dendrimer Multilayers Prepared from Layer-by-Layer Assembly Method
초록 Multilayer thin films of anionic Au nanoparticles (AuNPs) and cationic phosphorus dendrimers were deposited on 3-aminopropyldimethylsilane-coated substrates using layer-by-layer (LbL) assembly based on electrostatic interaction. The growth of the Au/dendrimer multilayers composed of AuNPs with the diameter of about 3 nm and 16 nm and 2 nm-sized dendrimer was monitored by UV-vis spectroscopy. The Au-containing multilayers have two surface plasmon bands at ~530 nm and ~600 nm, and the latter exhibits red-shift upon increasing the areal density of AuNPs as well as the increase of the layer number. These results demonstrate that the near-field coupling between the surface plasmons is responsible for the controlled absorption behavior.
저자 조문파1, 박정주2, 조진한2, 김동하1
소속 1이화여자대, 2국민대
키워드 surface plasmon; Au; nanoparticle; layer-by-layer; self-assembly
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