| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
분자전자소재 및 소자 |
| 제목 |
Synthesis and characterizations of phenanthrene polymer derivatives with high Voc for organic solar cells |
| 초록 |
In recent times, there has been considerable interest about organic solar cells (OSCs) due to lightweight, inexpensive, and flexible characteristics. Conventional thiophene derivatives have shown a high power conversion efficiency by relatively high short circuit current and fill factor. However, they are limited by relatively low open circuit voltage (Voc) due to high HOMO (highest occupied molecular orbital) level. Generally, poly(2,7-phenanthrenylene) derivatives have large band gap and deep HOMO level compared to P3HT, and it has chance to achieve higher Voc. In this presentation, we synthesized novel donor polymers containing phenanthrene backbone for improved Voc with push-pull structure to absorb wide range of the solar spectrum. We will present the synthesis and characterization of novel low band gap donor polymers which have different solubilizing group and accepting units. |
| 저자 |
김영아1, 임보규2, 정형구1, 김미경3, 김남구4, 윤진문5, 장수영1, 김인복6, 김동유1
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| 소속 |
1광주과학기술원 신소재공학과, 2Univ. of California Santa Barbara, 3광주과학기술원 광공학응용물리학제전공, 4히거신소재연구센터, 5광주과학기술원 나노바이오재료전자공학과, 6The Program for Integrated Molecular Systems (PIMS) |
| 키워드 |
organic solar cells; phenanthrene; high open circuit voltage
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| E-Mail |
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